c BN增强(Ti,W)C基复合金属陶瓷刀具材料的研制
2018-02-02
作者:李祥龙,方斌,牌君君,徐明,马宵 单位:齐鲁工业大学
摘要:采用热压烧结制备了不同亚微米级cBN含量的(Ti,W)C基复合金属陶瓷刀具材料,用热场发射扫描电子显微镜及能谱仪、透射电子显微镜和X射线衍射仪对材料的微观组织结构和力学性能进行了研究。结果表明:添加cBN可改善材料的力学性能,当cBN含量为1.5wt%时,(Ti,W)C基复合金属陶瓷刀具的性能最优,其抗弯强度达到917MPa,断裂韧性为9.27MPa·m1/2,维氏硬度为20.64GPa;适量cBN可起到细化晶粒、减少气孔缺陷和提高致密度的作用,复合材料由沿晶断裂为主转变为穿晶断裂为主;在cBN复合(W,Ti)C基金属陶瓷刀具材料中,主要的增韧补强机理有晶粒细化、颗粒桥联、裂纹偏转和裂纹分叉。
关键词:cBN;(Ti,W)C;热压烧结;金属陶瓷;增韧补强
中图分类号:TG711;TH140.7;TB331文献标志码:A
Study on Cubic Boron Nitride Reinforced (W,Ti)CBased
Composite Metal Ceramic Tool Material
Li Xianglong,Fang Bin,Pai Junjun,Xu Ming,Ma Xiao
Abstract:(Ti,W)C based composite cermet tool materials with different cBN contents are prepared by hot-pressing sintering.The microstructures and mechanical properties of the composites are studied by using field emission scanning electron microscope and energy dispersive Xray spectrometer,transmission electron microscope and Xray diffractometer.The results show that the addition of cBN can improve the mechanical properties of the composites. When the content of cBN is 1.5wt%,the mechanical properties of (W,Ti) Cbased composite cermets are the best.Its flexural strength reaches 917MPa,fracture toughness 9.27MPa·m1/2 and Vickers hardness 20.64GPa.It is found that the proper content of cBN can refine the grain effectively,improve the density and reduce the defects such as cavities. With the addition of cBN,the fracture form of composite can change from intergranular fracture to transgranular fracture,the fracture mode changes can effectively improve the mechanical properties of composite materials.In cBN composite(W,Ti) C matrix cermet tool materials,the main toughening mechanism is grain refinement,particle bridging,crack deflection and crack bifurcation.
Keywords:cubic boron nitride;titanium tungsten carbides;hot pressing sintering;cermet;toughening and reinforcing